The impact of pyrite variability, dispersive transport and precipitation of secondary phases on the sulphate release due to pyrite weathering

The objective of this study was to investigate the impact of flow, transport and geochemical parameters in the unsaturated and saturated zones on the release of SO₄ from overburden lignite spoil piles into the adjacent lake. A vertical one-dimensional model was set up using the reactive transport simulator SULFIDOX in order to account for the unsaturated zone. The SULFIDOX model was calibrated for effective diffusion using measured O₂ in the gas phase and SO₄ concentrations in the liquid phase from the unsaturated zone of the heap. The results show high sensitivity to O₂ supply and initially present gypsum, but the inclusion of secondary mineral precipitation in equilibrium is of minor importance for the results. To account for the transport of released SO₄ from the saturated zone into the surface water, scenarios were performed by using SULFIDOX results as input concentration for a two-dimensional vertical model set up with PROCESSING MODFLOW and MT3D. These scenarios indicate a rising discharge of SO₄ into the adjacent lake due to continued pyrite weathering for 80 a. Results are highly sensitive to dispersivity, whereas the spatial variability of pyrite distribution did not show any influence on the results. The consideration of initially present gypsum shows a major effect on the modelled SO₄ release.     

Vegetation Pattern in Northern Tibet in Relation to Environmental and Geo-spatial Factors

Environmental and Geo-spatial factors have long been considered as crucial determinants of species composition and distributions. However, quantifying the relative contributions of these factors for the alpine ecosystems is lacking. The Tibetan Plateau has a unique ecological environment and vegetation types. Our objectives are to quantify the spatial distributions of plant communities on the Northern Tibetan Alpine grasslands and to explore the relationships between vegetation composition, Geo-spatial factors and environmental factors. We established 63 field plots along a 1200-km gradient on the Northern Tibetan Plateau Alpine Grassland and employed the two-way indicator species analysis (TWINSPAN) and the detrended canonical correspondence analysis (DCCA). Fourteen communities of alpine grassland were identifiable along the transect and consisted of three vegetation types: Alpine meadow, Alpine steppe, and desert steppe. Vegetation composition and spatial distribution appeared to be largely determined by mean annual precipitation and less influenced by temperature. A large fraction (73.5%) of the variation in vegetation distribution was explained by environmental variables along this transect, somewhat less by Geo-spatial factors (56.3%). The environmental and Geo-spatial factors explained 29.6% and 12.3% of the total variation, respectively, while their interaction explained 43.9%. Our findings provide strong empirical evidence for explaining biological and environmental synergetic relationships in Northern Tibet.     

VIRGO: Experiment for helioseismology and solar irradiance monitoring

The scientific objective of the VIRGO experiment (Variability of solar IRradiance and Gravity Oscillations) is to determine the characteristics of pressure and internal gravity oscillations by observing irradiance and radiance variations, to measure the solar total and spectral irradiance and to quantify their variability over periods of days to the duration of the mission. With these data helioseismological methods can be used to probe the solar interior. Certain characteristics of convection and its interaction with magnetic fields, related to, for example, activity, will be studied from the results of the irradiance monitoring and from the comparison of amplitudes and phases of the oscillations as manifest in brightness from VIRGO, in velocity from GOLF, and in both velocity and continuum intensity from SOI/MDI. The VIRGO experiment contains two different active-cavity radiometers for monitoring the solar constant, two three-channel sunphotometers (SPM) for the measurement of the spectral irradiance at 402, 500 and 862 nm, and a low-resolution imager (LOI) with 12 pixels, for the measurement of the radiance distribution over the solar disk at 500 um. In this paper the scientific objectives of VIRGO are presented, the instruments and the data acquisition and control system are described in detail, and their measured performance is given.died 13 October 1994     

Regulation of eelgrass (Zostera marina) cover along depth gradients in Danish coastal waters

A large data set, collected under the national Danish monitoring program, was used to evaluate the importance of photon flux density (PFD), relative wave exposure (REI), littoral slope, and salinity in regulating eelgrass cover at different depth intervals in Danish coastal waters. Average eelgrass cover exhibited a bell-shaped pattern with depth, reflecting that different factors regulate eelgrass cover at shallow- and deep-water sites. The multiple logistic regression analysis was used to identify regulating factors and determine their role in relation to eelgrass cover at different depth intervals. PFD, REI, and salinity were main factors affecting eelgrass cover while littoral slope had no significant effect. Eelgrass cover increased with increasing PFD at water depths of more than 2 m, while cover was in versely related to REI in shallow water. This pattern favored eelgrass cover at intermediate depths where levels of PFD and REI were moderate. Salinity had a minor, but significant, effect on eelgrass cover that is most likely related to the varying costs of osmoregulation with changing salinity. The analysis provided a useful conceptual framework for understanding the factors that regulate eelgrass abundance with depth. Although the regression model was statistically significant and included the factors generally considered most important in regulating eelgrass cover, its explanatory power was low, especially in shallow water. The largest discrepancies between predicted and observed values of cover appeared in cases where no eelgrass occurred despite sufficient light and moderate levels of exposure (almost 50% of all observations). These discrepancies suggest that population losses due to stochastic phenomena, such as extreme wind events, played an important regulating role that is not adequately described by average exposure levels. A more thorough knowledge of the importance of such loss processes and the time scales involved in recovery of seagrass populations after a severe disturbance are necessary if we are to understand the regulation of seagrass distribution in shallow coastal areas more fully.     

Reconstruction of the volcanic history of the Tacámbaro-Puruarán area (Michoacán, México) reveals high frequency of Holocene monogenetic eruptions

The 690?km² Tacámbaro-Puruarán area located at the arc-front part of the Michoácan-Guanajuato volcanic field in the Trans-Mexican Volcanic Belt (TMVB) records a protracted history of volcanism that culminated with intense monogenetic activity in the Holocene. Geologic mapping, ⁴⁰Ar/³⁹Ar and ¹⁴C radiometric dating, and whole-rock chemical analyses of volcanic products provide insights to that history. Eocene volcanics (55–40?Ma) exposed at uplifted blocks are related to a magmatic arc that preceded the TMVB. Early TMVB products are represented by poorly exposed Pliocene silicic domes (5–2?Ma). Quaternary (<2?Ma) volcanoes (114 mapped) are mainly scoria cones with lavas (49 vol.%), viscous lava flows (22 vol.%), and lava shields (22 vol.%). Erupted products are dominantly either basaltic andesites (37 vol. %), or andesites (17 vol.%), or span across both compositions (28 vol.%). Basalts (9 vol.%), dacites (4 vol.%), shoshonites (2 vol.%), and other alkali-rich rocks (<3 vol.%) occur subordinately. Early-Pleistocene volcanism was bimodal (dacites and basalts) and voluminous while since 1?Ma small-volume eruptions of intermediate magmas have dominated. Higher rates of lithospheric extension in the Quaternary may have allowed a larger number of small, poorly evolved dikes to reach the surface during this period. Eruptive centers as old as 1.7?Ma are aligned in a NE direction parallel to both, basement faults and the direction of regional compressive stress, implying structural control on volcanic activity. Data suggest that volcanism was strongly pulsatory and fed by localized low-degree partial melting of mantle sources. In the Holocene, at least 13 eruptions occurred (average recurrence interval of 800?years). These produced ~3.8?km³ of basaltic andesitic to andesitic magma and included four eruptions dated at ~1,000; 4,000; 8,000; and 11,000?years bc (calibrated ¹⁴C ages). To date, this is one of the highest monogenetic eruption frequencies detected within such a small area in a subduction-related arc-setting. These anomalous rates of monogenetic activity in an area with thick crust (>30?km) may be related to high rates of magma production at depth and a favorable tectonic setting.     

Total Solar Irradiance Observations

The record of total solar irradiance (TSI) during the past 35?years has overlapping observations from space which can be merged to a composite, and three are available, namely the PMOD, the ACRIM and the IRMB composites. There are important differences between them, which are discussed in detail in order to find the best representation of solar variability during the last three cycles, for the following discussions of solar irradiance variability. Moreover, the absolute value of TSI from TIM on SORCE is 1,361?Wm^?2, substantially lower than the value 1,365?Wm^?2, which was observed by the classical radiometers. New results from specific experiments are now available, which are discussed in order to define the value to be used in, e.g., climate models. The most important issue regarding the recent TSI records is the low value observed during the minimum in 2009, which is 25% of a typical cycle amplitude lower than the value in 1996. The validity of this low value has been confirmed by comparing all existing TSI observations during cycle 23. On the other hand, activity indices, such as the sunspot number, the 10.7-cm radio flux (F10.7), the CaII and MgII indices and also the Ly-α irradiance or the frequency changes in low-order p modes, show a much smaller decreases relative to their respective typical cycle amplitude. It is most likely that an increasing contrast of the facular and network elements with decreasing magnetic field is responsible for this discrepancy. The value of TSI at minima is correlated with the open magnetic field of the Sun, B _R,?at minima. Using B _R at minima, interpolated linearly in between as a fourth component of a proxy model based on the photometric sunspot index and on the MgII index improves the explanation of the variance of TSI over the full period of the last three solar cycles to 84.7%. Results from other models are also discussed.     

Optimizing Wellfield Operation in a Variable Power Price Regime

Wellfield management is a multiobjective optimization problem. One important objective has been energy efficiency in terms of minimizing the energy footprint (EFP) of delivered water (MWh/m³). However, power systems in most countries are moving in the direction of deregulated markets and price variability is increasing in many markets because of increased penetration of intermittent renewable power sources. In this context the relevant management objective becomes minimizing the cost of electric energy used for pumping and distribution of groundwater from wells rather than minimizing energy use itself. We estimated EFP of pumped water as a function of wellfield pumping rate (EFP‐Q relationship) for a wellfield in Denmark using a coupled well and pipe network model. This EFP‐Q relationship was subsequently used in a Stochastic Dynamic Programming (SDP) framework to minimize total cost of operating the combined wellfield‐storage‐demand system over the course of a 2‐year planning period based on a time series of observed price on the Danish power market and a deterministic, time‐varying hourly water demand. In the SDP setup, hourly pumping rates are the decision variables. Constraints include storage capacity and hourly water demand fulfilment. The SDP was solved for a baseline situation and for five scenario runs representing different EFP‐Q relationships and different maximum wellfield pumping rates. Savings were quantified as differences in total cost between the scenario and a constant‐rate pumping benchmark. Minor savings up to 10% were found in the baseline scenario, while the scenario with constant EFP and unlimited pumping rate resulted in savings up to 40%. Key factors determining potential cost savings obtained by flexible wellfield operation under a variable power price regime are the shape of the EFP‐Q relationship, the maximum feasible pumping rate and the capacity of available storage facilities.     

Ageing of Dissolved Halogenated Humic Substances and the Microbiological Influence on this Process

The distribution of halogens in various fractions of humic substances (HS), separated by their molecular weight, was found to be different for the different halogens. This was demonstrated for chlorine, bromine, and iodine in sewage and brown water samples by applying inductively coupled plasma mass spectrometry coupled with size‐exclusion chromatography. Quantification of the different fractions of iodinated humic substances was obtained by quadrupole mass spectrometry in connection with the isotope dilution technique using an ¹²⁹I‐enriched spike solution. Quantitative analysis was not possible for the corresponding chlorine and bromine species because of spectrometric interferences in the quadrupole instrument. The ageing of HS/halogen species was followed with respect to possible transformations of these species in a ground and sewage water sample up to eight weeks. Even if a distinct structural variation of the humic substance was observed with time by measuring the UV absorption, chlorine remained in the same molecular weight fraction and only a small change was found for the HS/bromine species after eight weeks. In contrast to these findings a substantial transformation of HS/iodine compounds took place, which demonstrated that the transfer probability of halogens from one to another HS fraction is increased with decreasing strength of the halogen bond to carbon. By comparing the results of an original sewage water sample with a filtered one and with another one which was enriched by microorganisms cultivated from the same original sample, a strong microbiological influence on the transformation of HS/iodine species was found. A quantitative balance of the corresponding HS/iodine fractions was calculated for an ageing period of eight weeks showing that iodine was preferably transferred to newly formed UV active HS substances of high molecular weight. In total, no iodine was released from the humic substances.     

Degradation and Transformation of Aquatic Humic Substances by Laccase-producing Fungi Cladosporium cladosporioides and Polyporus versicolor

A phenoloxidase-producing fungus – Cladosporium cladosporioides – was isolated from water of a bog lake. At high concentrations of carbon (333 mM) and nitrogen (12 mM), the fungus demonstrated the formation of a laccase and a high ligninolytic activity. After addition of riverine or groundwater humic substances into culture media (ca. 1 mg mL^–1), the fungus showed the ability of degrading (utilizing) of about 60% of these substances. However, the exact quantification of the degree of degradation was difficult because of adsorption of humic matter on fungal mycelium. Reisolated humic substances were lower in aromatic and higher in aliphatic structures. A crude enzyme from the C. cladosporioides culture showed only low activity in decolorizing humic substances, whereas decolorization up to 50% was observed when using a laccase preparation from Polyporus versicolor, and especially in the presence of a redox mediator.